Subscriber access provided by Massachusetts Institute of Technology
J. Phys. Soc. Jpn. 82, 084003 (2013) [10 Pages]
FULL PAPERS

Drag Coefficient of a Rigid Spherical Particle in a Near-Critical Binary Fluid Mixture

Jun-ichi Fukuda
JPSJ News Comments 10,  15 (2013).

+ Affiliations
1Fukui Institute for Fundamental Chemistry, Kyoto University, Kyoto 606-8103, Japan2School of Fundamental Science and Technology, Keio University, Yokohama 223-8522, Japan3Department of Chemistry, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan

We calculate the drag coefficient of a rigid spherical particle in an incompressible binary fluid mixture. A weak preferential attraction is assumed between the particle surface and one of the fluid components, and the difference in the viscosity between the two components is neglected. Using the Gaussian free-energy functional and solving the hydrodynamic equation explicitly, we can show that the preferential attraction makes the drag coefficient larger as the bulk correlation length becomes longer. The dependence of the deviation from the Stokes law on the correlation length, when it is short, turns out to be much steeper than the previous estimates.

©2013 The Author(s)
This article is published by the Physical Society of Japan under the terms of the Creative Commons Attribution 4.0 License. Any further distribution of this work must maintain attribution to the author(s) and the title of the article, journal citation, and DOI.

References

  • 1 B. V.Derjaguin and L. D.Landau: Acta Physicochim. (USSR) 14 (1941) 633. Google Scholar
  • 2 E. J. W.Verwey and J. Th. G.Overbeek: Theory of the Stability of Lyophobic Colloids (Elsevier, Amsterdam, 1948) Chaps. 8-12. Google Scholar
  • 3 W. B.Russel, D. A.Saville, and W. R.Schowalter: Colloidal Dispersions (Cambridge University Press, Cambridge, U.K., 1989) Chaps. 1-5. CrossrefGoogle Scholar
  • 4 G. G.Stokes: Trans. Cambridge Philos. Soc. 9 (1851) 8. Google Scholar
  • 5 W.Sutherland: Philos. Mag. 9 (1905) 781. CrossrefGoogle Scholar
  • 6 A.Einstein: Ann. Phys. (Leipzig) 322 (1905) 549. CrossrefGoogle Scholar
  • 7 D.Beysens and D.Estève: Phys. Rev. Lett. 54 (1985) 2123. CrossrefGoogle Scholar
  • 8 B. M.Law, J.-M.Petit, and D.Beysens: Phys. Rev. E 57 (1998) 5782. CrossrefGoogle Scholar
  • 9 J.-M.Petit, B. M.Law, and D.Beysens: J. Colloid Interface Sci. 202 (1998) 441. CrossrefGoogle Scholar
  • 10 D.Beysens and T.Narayanan: J. Stat. Phys. 95 (1999) 997. CrossrefGoogle Scholar
  • 11 H.Guo, T.Narayanan, M.Sztuchi, P.Schall, and G. H.Wegdam: Phys. Rev. Lett. 100 (2008) 188303. CrossrefGoogle Scholar
  • 12 D.Bonn, J.Otwinowski, S.Sacanna, H.Guo, G.Wegdam, and P.Schall: Phys. Rev. Lett. 103 (2009) 156101. CrossrefGoogle Scholar
  • 13 M. E.Fisher and P. G.de Gennes: C. R. Seances Acad. Sci., Ser. B 287 (1978) 207. Google Scholar
  • 14 C.Hertlein, L.Helden, A.Gambassi, S.Dietrich, and C.Bechinger: Nature 451 (2008) 172. CrossrefGoogle Scholar
  • 15 A.Gambassi, A.Macioek, C.Hertlein, U.Nellen, L.Helden, C.Bechinger, and S.Dietrich: Phys. Rev. E 80 (2009) 061143. CrossrefGoogle Scholar
  • 16 R.Okamoto and A.Onuki: J. Chem. Phys. 136 (2012) 114704. CrossrefGoogle Scholar
  • 17 Ya. A.Bal'tsevich, V. G.Martynets, and E. V.Matizen: Zh. Eksp. Teor. Fiz. 51 (1966) 983 [Sov. Phys. JETP 24 (1967) 654]. Google Scholar
  • 18 V. G.Martynets and E. V.Matizen: Zh. Eksp. Teor. Fiz. 58 (1970) 430 [Sov. Phys. JETP 31 (1970) 228]. Google Scholar
  • 19 S. P.Lee: Phys. Rev. Lett. 36 (1976) 1319. CrossrefGoogle Scholar
  • 20 K. B.Lyons, R. C.Mockler, and W. J.O'Sullivan: Phys. Rev. Lett. 30 (1973) 42. CrossrefGoogle Scholar
  • 21 K. B.Lyons, R. C.Mockler, and W. J.O'Sullivan: Phys. Rev. A 10 (1974) 393. CrossrefGoogle Scholar
  • 22 Y.Nakamura, A.Yoshimori, and R.Akiyama: J. Phys. Soc. Jpn. 81 (2012) SA026. LinkGoogle Scholar
  • 23 B. A.Camley and F. L. H.Brown: Phys. Rev. E 85 (2012) 061921. CrossrefGoogle Scholar
  • 24 J. W.Cahn: J. Chem. Phys. 66 (1977) 3667. CrossrefGoogle Scholar
  • 25 P. C.Hohenberg and B. I.Halperin: Rev. Mod. Phys. 49 (1977) 435. CrossrefGoogle Scholar
  • 26 A.Onuki: Phase Transition Dynamics (Cambridge University Press, Cambridge, U.K., 2002) Chap. 6. CrossrefGoogle Scholar
  • 27 S. R.de Groot and P.Mazur: Non-Equilibrium Thermodynamics (Dover, New York, 1984) Chap. 4. Google Scholar
  • 28 Y.Fujitani: J. Phys. Soc. Jpn. 76 (2007) 064401. LinkGoogle Scholar
  • 29 To calculate the integral with respect to σ, we replaced 1=ζc with a variable α in the integrand, took eα/(1 + α−1), which lies in Eq. (3.4), out of the integral sign, and added the option “Assumptions ₒ ρ ≥ 1 && α > 0”. Google Scholar
  • 30 A.Onuki, R.Okamoto, and T.Araki: Bull. Chem. Soc. Jpn. 84 (2011) 569. CrossrefGoogle Scholar
  • 31 A.Onuki and R.Okamoto: Curr. Opin. Colloid Interface Sci. 16 (2011) 525. CrossrefGoogle Scholar
  • 32 R.Okamoto and A.Onuki: Phys. Rev. E 82 (2010) 051501. CrossrefGoogle Scholar
  • 33 R.Okamoto and A.Onuki: Phys. Rev. E 84 (2011) 051401. CrossrefGoogle Scholar
  • 34 S.Samin and Y.Tsori: Europhys. Lett. 95 (2011) 36002. CrossrefGoogle Scholar
  • 35 U.Nellen, J.Dietrich, L.Helden, S.Chodankar, K.Nygård, J. F.van der Veen, and C.Bechinger: Soft Matter 7 (2011) 5360. CrossrefGoogle Scholar
  • 36 J.-C.Desplat, I.Pagonabarraga, and P.Bladon: Comput. Phys. Commun. 134 (2001) 273. CrossrefGoogle Scholar
  • 37 K.Stratford, R.Adhikari, I.Pagonabarraga, and J.-C.Desplat: J. Stat. Phys. 121 (2005) 163. CrossrefGoogle Scholar
  • 38 T.Araki and H.Tanaka: Phys. Rev. E 73 (2006) 061506. CrossrefGoogle Scholar
  • 39 T.Araki and H.Tanaka: J. Phys.: Condens. Matter 20 (2008) 072101. CrossrefGoogle Scholar
  • 40 M. E.Cates and P. S.Clegg: Soft Matter 4 (2008) 2132. CrossrefGoogle Scholar
  • 41 E.Kim, K.Stratford, R.Adhikari, and M. E.Cates: Langmuir 24 (2008) 6549. CrossrefGoogle Scholar
  • 42 H.Fukagawa and Y.Fujitani: Prog. Theor. Phys. 127 (2012) 921. CrossrefGoogle Scholar
  • 43 Y.Fujitani: J. Phys. Soc. Jpn. 70 (2001) 1556. LinkGoogle Scholar
  • 44 Y.Fujitani: J. Phys. Soc. Jpn. 79 (2010) 074002. LinkGoogle Scholar
  • 45 C.Bender and S. A.Orszag: Advanced Mathematical Methods for Scientists and Engineers (Springer, New York, 1999) Chap. 1. CrossrefGoogle Scholar