J. Phys. Soc. Jpn. 89, 051014 (2020) [9 Pages]
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SPECIAL TOPICS: Frontier of Hydrogen Science

Multimetallic Rare Earth and Group 4 Transition Metal Hydrides for Novel Transformations of Small Molecules

Takanori Shima1,2,
+ Affiliations
1Advanced Catalysis Research Group, RIKEN Center for Sustainable Resource Science, Wako, Saitama 351-0198, Japan2Organometallic Chemistry Laboratory, RIKEN Cluster for Pioneering Research, Wako, Saitama 351-0198, Japan
Received September 13, 2019; Accepted November 11, 2019; Published February 25, 2020

Hydrogenolysis of mono(cyclopentadienyl (Cp))-ligated rare earth metal alkyl complexes with H2 affords a variety of multimetallic rare earth hydride complexes, which can serve as a unique platform for activation of various substrates such as CO, CO2, H2, and unsaturated C–C and C–N bonds. By using the mono-Cp-ligated rare earth species as a building block, novel d–f heteromultimetallic hydride complexes could be prepared, which show some interesting reactivities toward small molecules such as C–O bond cleavage and C–C bond formation of CO, and reversible H2 uptake and release under crystalline form. A titanium hydride complex shows high activity toward inert molecules such as N–N bond cleavage and N–H bond formation of N2, C–C bond cleavage and rearrangement of benzene, and hydrodenitrogenation of pyridines under mild conditions. These reactions are induced by synergistic effects of multiple metal hydrides.

©2020 The Physical Society of Japan
https://doi.org/10.7566/JPSJ.89.051014

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