JPS Conf. Proc. 30, 011120 (2020) [6 pages]
Proceedings of the International Conference on Strongly Correlated Electron Systems (SCES2019)
Optical Conductivity Study of f Electron States in YbCu2Ge2 at High Pressures to 20 GPa
1Graduate School of Advanced Technology and Science, Tokushima University, Tokushima 770-8506, Japan
2Graduate School of Science, Kobe University, Kobe 657-8501, Japan
3Faculty of Science, University of the Ryukyus, Okinawa 903-0213, Japan
4Japan Synchrotron Radiation Research Center, Sayo, Hyogo 679-5198, Japan
Graduate School of Natural Science and Technology, Shimane University, Matsue 690-8504, Japan
Received September 10, 2019

Optical conductivity [\(\sigma (\omega )\)] of YbCu2Ge2 has been measured at external pressures (P) to 20 GPa, to study the P evolution of f electron hybridized states. At P = 0, \(\sigma (\omega )\) shows a marked mid-infrared (mIR) peak at 0.37 eV, which is due to optical excitations from f14 (Yb2+) state located below the Fermi level. With increasing P, the mIR peak shows significant shifts to lower energy, reaching 0.18 eV at P = 20 GPa. This result indicates that the f14 energy level increases toward the Fermi level with P. Such a shift of the f electron level with P has been expected from theoretical considerations, but had never been demonstrated by spectroscopic experiment under high P. The obtained results are also analyzed in terms of the P evolution of the conduction-f electron hybridization.

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